The 24-year-old hunk, who plays Dan Humphries in the teen drama, took to Fifth Ave. to shoot his parts slated for the upcoming fifth season - which premieres on September 19th.
And it looks like Penn will have a new guy to contend with this season, as "Stargate Universe" actor Brian J. Smith has just joined the hit CW show.
Smith is set to play Max, the new love interest of the Blake Lively-fronted character Serena van der Woodsen.
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